金红石
电化学
氧化物
扫描隧道显微镜
分解水
材料科学
水溶液
原子单位
化学物理
纳米技术
光催化
化学工程
电极
化学
物理化学
催化作用
物理
生物化学
量子力学
工程类
冶金
作者
Yan Sun,Chengrong Wu,Feng Wang,Ruihao Bi,Yong‐Bin Zhuang,Shuai Liu,Mingshu Chen,Kelvin H. L. Zhang,Jiawei Yan,Bing‐Wei Mao,Zhong‐Qun Tian,Jun Cheng
标识
DOI:10.26434/chemrxiv-2023-7wsqv
摘要
Metal oxides are promising (photo)electrocatalysts for sustainable energy technologies due to their good activity and abundant resources. Their applications such as photocatalytic water splitting predominantly involve aqueous inter- faces at electrochemical conditions, but in situ probing oxide-water interfaces is proven to be extremely challenging. Here, we present an electrochemical scanning tunneling microscopy (EC-STM) study on the rutile TiO2(110)-water interface, and by tuning surface redox chemistry with careful potential control we are able to obtain high quality images of interfacial structures with atomic details. It is interesting to find that the interfacial water exhibits an unexpected double-row pattern that has never been observed. This finding is confirmed by performing a large scale simulation of a stepped interface model enabled by machine learning accelerated molecular dynamics (MLMD) at ab initio accuracy. Furthermore, we show that this pattern is induced by the steps present on the surface, which can propagate across the terraces by interfacial hydrogen bonds. Our work demonstrates that by combining EC-STM and MLMD we can obtain new atomic details of interfacial structures that are valuable to understand the activity of oxides at realistic conditions.
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