化学
催化作用
酒精氧化
比例(比率)
组合化学
有机化学
物理
量子力学
作者
Kexue Xing,Jicong Xiang,Zijin Luo,Guiyuan Liu,Xianghao Zhang,Guofu Zhang,Chengrong Ding
标识
DOI:10.1002/ejoc.202400804
摘要
Abstract Since the report of oxamide ligands, they have been widely used for the efficient construction of various types of C−X (such as C, N, O and S) bonds. To evaluate whether the easily tunable electronic properties and unique coordination modes of oxamide ligands can also shine in the field of oxidation, we initiated a study on oxamide ligand/copper/air oxidation and applied it to the oxidation of alcohols to assess its practicality and potential applications. The practicality of this strategy was further verified through scale‐up reactions on a 100 mmol scale and gram‐scale derivatization of pharmaceutical molecules.
科研通智能强力驱动
Strongly Powered by AbleSci AI