化学
氰化物
氰化氢
群(周期表)
主组元素
碱金属
共价键
无机化学
有机化学
过渡金属
催化作用
作者
Axel Schulz,Jonas Surkau
出处
期刊:Reviews in Inorganic Chemistry
[De Gruyter]
日期:2022-09-21
卷期号:43 (1): 49-188
被引量:11
标识
DOI:10.1515/revic-2021-0044
摘要
Abstract Homoleptic cyanide compounds exist of almost all main group elements. While the alkali metals and alkaline earth metals form cyanide salts, the cyanides of the lighter main group elements occur mainly as covalent compounds. This review gives an overview of the status quo of main group element cyanides and cyanido complexes. Information about syntheses are included as well as applications, special substance properties, bond lengths, spectroscopic characteristics and computations. Cyanide chemistry is presented mainly from the field of inorganic chemistry, but aspects of chemical biology and astrophysics are also discussed in relation to cyano compounds.
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