Validation of the Cossee–Arlman mechanism for propylene oligomerization on Ni/UiO-66
机制(生物学)
催化作用
化学
组合化学
有机化学
物理
量子力学
作者
Benjamin Yeh,Saumil Chheda,Jian Zheng,Julian Schmid,Laura Löbbert,Ricardo Bermejo‐Deval,Oliver Y. Gutiérrez,Johannes A. Lercher,Laura Gagliardi,Aditya Bhan
Steady state rate expressions can be derived to distinguish the Cossee–Arlman and metallacycle mechanisms postulated for propylene oligomerization on nickel-based catalysts based on product selectivities.