A Universal Single‐Atom Coating Strategy Based on Tannic Acid Chemistry for Multifunctional Heterogeneous Catalysis

Here, we report a universal single-atom coating (SAC) strategy by taking advantage of the rich chemistry of tannic acid (TA). TA units not only self-assemble into a cross-linked porous polyphenolic framework, but also can grip on different substates via multiple binding modes. Benefiting from the diverse chelating ability of TA, a series of mono-, and bi-metallic SACs can be formed on substrates of different materials (e. g., carbon, SiO2 , TiO2 , MoS2 ), dimensions (0D-3D) and sizes (50 nm-5 cm). By contrast, uniform SAC cannot be achieved using common approaches such as pyrolysis of metal-dopamine complexes or metal-organic frameworks. As a proof-of-concept demonstration, two Co SACs immobilized on graphene and TiO2 were prepared. The former one shows six-fold higher mass activity than Pt/C toward oxygen reduction. The latter one displays outstanding photocatalytic activity owing to the high activity of the single atoms and the formation of the single-atom coating-TiO2 heterojunction.