Research Progress in Semiconductor Materials with Application in the Photocatalytic Reduction of CO2

The large-scale burning of non-renewable fossil fuels leads to the gradual increase of the CO2 concentration in the atmosphere, which is associated with negative impacts on the environment. The consequent need to reduce the emission of CO2 resulting from fossil fuel combustion has led to a serious energy crisis. Research reports indicate that the photocatalytic reduction of CO2 is one of the most effective methods to control CO2 pollution. Therefore, the development of novel high-efficiency semiconductor materials has become an important research field. Semiconductor materials need to have a structure with abundant catalytic sites, among other conditions, which is of great significance for the practical application of highly active catalysts for CO2 reduction. This review systematically describes various types of semiconductor materials, as well as adjustments to the physical, chemical and electronic characteristics of semiconductor catalysts to improve the performance of photocatalytic reduction of CO2. The principle of photocatalytic CO2 reduction is also provided in this review. The reaction types and conditions of photocatalytic CO2 reduction are further discussed. We believe that this review will provide a good basis and reference point for future design and development in this field.