电解质
石墨
介电谱
电化学
X射线光电子能谱
阳极
材料科学
碳酸盐
无机化学
化学
化学工程
分析化学(期刊)
电极
有机化学
物理化学
复合材料
冶金
工程类
作者
I. A. Profatilova,Sung‐Soo Kim,Nam‐Soon Choi
标识
DOI:10.1016/j.electacta.2009.03.032
摘要
The influence of fluoroethylene carbonate (FEC) on the electrochemical and thermal properties of graphite anodes is examined. The dQ/dV graph of graphite/Li cells shows that the electrochemical reduction peak of an electrolyte shifts to higher potential in the presence of FEC. The DSC results for graphite anodes cycled in FEC-containing electrolytes clearly exhibit that an exothermic peak at around 120 °C mostly disappears. It is demonstrated by X-ray photoelectron spectroscopy (XPS) and electrochemical impedance spectroscopy (EIS) that SEI formed by the electrochemical reduction of FEC consists of a relatively high proportion of LiF and gives low interfacial resistance for graphite/Li/Li cells.
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