The gelatinization and retrogradation properties of wheat starch with the addition of stearic acid and sodium alginate

回生(淀粉) 硬脂酸 差示扫描量热法 结晶度 食品科学 化学 淀粉 抗性淀粉 核化学 结晶学 有机化学 直链淀粉 热力学 物理
作者
Zhen Yu,Yu‐Sheng Wang,Hai‐Hua Chen,Qianqian Li,Qi Wang
出处
期刊:Food Hydrocolloids [Elsevier BV]
卷期号:81: 77-86 被引量:108
标识
DOI:10.1016/j.foodhyd.2018.02.041
摘要

Abstract The gelatinization and retrogradation properties of wheat starch (WS) with the addition of the combination of stearic acid and sodium alginate (C-SA-AG) were investigated in this study. The results of differential scanning calorimetry (DSC) showed that C-SA-AG significantly increased the gelatinization onset temperature of WS by 2.6–3.4 °C, whereas decreased the gelatinization enthalpy of WS by 5.7–6.7 J/g. This suggested that C-SA-AG could obviously delay the gelatinization process of WS. The gel firmness, retrogradation enthalpy, the ratio of intensity at the band of 1047 cm−1 to 1022 cm−1 (R1047/1022), and the relative crystallinity (RC) of WS were significantly decreased with the addition of C-SA-AG by 322–346 g, 0.51–1.78 J/g, 0.06–0.12, and 7.12–9.05% after stored for 7 days at 4 °C, respectively. However, the loss factor (tanδt/tanδ0) was increased by 0.49–0.54 after sweeping for 120 min. This suggested that C-SA-AG could effectively retard the retrogradation of WS. During storage, the retrograded WS containing SA showed V-type crystal structure, which lost the A-type crystal structure of native WS.
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