化学气相沉积
金属有机骨架
聚合物
金属
多孔介质
金属有机气相外延
化学
沉积(地质)
多孔性
第2组金属有机化学
纳米技术
甲醇
催化作用
化学工程
材料科学
有机化学
分子
外延
古生物学
吸附
沉积物
工程类
生物
图层(电子)
作者
Stephan Hermes,Marie‐Katrin Schröter,Rochus Schmid,Lamma Khodeir,Martin Muhler,Arno Tißler,Richard W. Fischer,Roland A. Fischer
标识
DOI:10.1002/anie.200462515
摘要
Precursors and particles captured in a net: Porous coordination polymers such as MOF-5 are efficient gas storage devices and are also able to absorb metal organic chemical vapor deposition (MOCVD) precursors (see picture, red: [(η5-C5H5)Pd(η3-C3H5)]). These incorporated compounds are easily reduced to give the corresponding metal nanoparticles. Applications in heterogeneous catalysis, for instance, methanol synthesis or hydrogenation, are described. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2005/z462515_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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