Local Environment-Modulated f–f Transition in Unit-Cell-Sized Lanthanide Ultrathin Nanostructures

The regulation of the f-f transition is the basis of utilizing the abundant optical properties of lanthanide (Ln), of which the key is to modulate the local environment of Ln ions. Here, we constructed Eu(III)-based unit-cell-sized ultrathin nanowires (UCNWs) with red luminescence and polymer-like behavior, which appears as an ideal carrier for regulating f-f transition. The f-f transition of Eu(III) in UCNWs could be precisely regulated through various ligands. It is the unusual surface states that make the UCNWs exhibit greater electric dipole strength and better sensitivity to various ligands compared with the carefully constructed ultrathin nanosheets. In addition, the possibility of regulating f-f transition in UCNWs through energy transfer and a high entropy strategy was also revealed. Finally, a temperature-dependent universal fluorescent ink was prepared based on UCNWs, which provides ideas for intelligent flexible fluorescent materials.