介电谱
降级(电信)
电池(电)
电化学
锂(药物)
材料科学
电阻抗
锂离子电池
加速老化
计算机科学
纳米技术
化学
电气工程
电极
复合材料
工程类
物理
物理化学
医学
量子力学
内分泌学
电信
功率(物理)
作者
Wenxuan Hu,Yufan Peng,Yimin Wei,Yong Yang
标识
DOI:10.1021/acs.jpcc.3c00033
摘要
An in-depth understanding of battery degradation and aging in-Operando not only plays a vital role in the design of battery managing systems but also helps to ensure safe use and manufacturing optimization of lithium-ion batteries (LIBs) in large-scale applications. Electrochemical impedance spectroscopy (EIS) is a nondestructive method which unravels electrode kinetic processes inside the batteries in different time domains, including charge-transfer reactions, interfacial evolutions, and mass diffusions. It has become a powerful diagnosis and pre/prognosis tool in battery aging research, as it provides important insight into the changes of internal electrochemical processes by correlating the impedance evolution to degradation mechanisms. This review gives a critical overview on rapidly developing impedance techniques for degradation and aging investigation of Li-ion batteries. The EIS variations of LIBs at different aging conditions of calendar aging and accelerated aging are systematically summarized. In addition, the working principles, data validation, and modeling methods, including equivalent circuit model (ECM), distribution of relaxation times (DRT), and transmission line model (TLM), of classical EIS and dynamic EIS are elaborately concluded. Finally, the challenges and perspectives of further application of EIS in the aging research of LIBs are presented.
科研通智能强力驱动
Strongly Powered by AbleSci AI