微量气体
可调谐激光吸收光谱技术
甲烷
检出限
吸收(声学)
降噪
激光器
时滞与积分
灵敏度(控制系统)
卡尔曼滤波器
波长
吸收光谱法
计算机科学
分析化学(期刊)
光学
可调谐激光器
化学
材料科学
电子工程
光电子学
物理
色谱法
工程类
人工智能
有机化学
作者
Yongpeng Shi,Zhen Hu,Mingsheng Niu,Taohua Li,Hui Li,Huiyuan Liu,Xiangxian Li
标识
DOI:10.1016/j.snb.2024.135829
摘要
A high-precision gas detection system with a dual‐incidence multi-pass cell (D‐MPC) based on TDLAS was developed, which can simultaneously measure quadruple component gases. Two Distributed Feedback (DBF) Laser Diodes with central wavelength of 1654 nm and 2004 nm were utilized to measure methane (CH4) and carbon dioxide (CO2) for evaluating the performance of the system. High sensitivity and low frequency drift were accomplished by utilizing the second harmonic signals (WMS-2f) detection and peak-locking technology. A LabVIEW-based control and acquisition program, which could be used for direct absorption and wavelength modulation, was developed. Kalman adaptive filtering, Least Mean Squares (LMS) adaptive filtering and S-G filtering were employed for denoising in direct absorption spectroscopy (DAS), respectively, and optimal denoising technology of S-G filtering was selected. According to Allan deviation analysis, the optimal detection precision for CH4 and CO2 was 12 ppb at an integration time of 36 s and 270 ppb at an integration time of 43 s, respectively. A two-day continuous monitoring of atmospheric CO2 and CH4 was implemented to verify the system stability and can be applied to other trace gases monitoring.
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