A Flexible Multifunctional Cyanoethyl‐Modified Bacterial Cellulose Nanofiber Framework for High‐Energy and High‐Power Density Aqueous Li‐Ion Batteries

Abstract Aqueous rechargeable lithium‐ion batteries (ARLIBs) are extensively researched due to their inherent safety, typical affordability, and potential high energy density. However, fabricating ARLIBs with both high energy density and power performance remains challenging. Herein, based on cyanoethyl‐modified bacterial cellulose nanofibers (CBCNs), a multifunctional fast ion transport framework is developed to construct the flexible free‐standing ARLIBs with high areal loading and excellent rate performance. Benefiting from the unique merits of CBCNs, such as ultra‐high aspect ratio, excellent toughness, superior adhesion, good lithiophilicity and ideal stability, the flexible free‐standing and highly robust electrodes are fabricated and exhibit a long‐term stable cycling of 1200 cycles with a high specific capacity of 117 mAh∙g −1 at 15 C. Remarkably, the corresponding full cell with the free‐standing high mass loading (45.5 mg∙cm −2 ) electrodes under the condition of ultra‐low addition of battery binder demonstrates a cycle lifespan of over 1000 cycles with a specific capacity of 120 mAh∙g −1 and a capacity decay as low as 0.03% per cycle, which is far superior to those of almost all previous reports. This work provides a strategy for constructing ARLIBs with high energy density and power performance by introducing a unique fast ion transport nanofiber framework.