Performance enhancement and optimization of the anammox process with the addition of iron

This study was conducted to evaluate the performance of anammox reaction on the addition of iron. Iron was added in the form of FeSO4 starting with 2 mg/L (phase I), 5 mg/L (phase II), 8 mg/L (phase III), 10 mg/L (phase IV), 30 mg/L (phase V) and 50 mg/L (phase VI) on the addition of Fe (II) in anammox reactor. The efficiency of ammonia removal increased up to 90% with 5 mg/L of Fe (II) addition as compared to 77% when no Fe (II) was added. As the iron dosing was increased from 10 to 30 mg/L, ammonia removal declined sharply, which recovered slowly at steady-state condition. However, on the addition of 30 and 50 mg/L of Fe (II), the efficiency declined to 55% and 44%, respectively and did not recover. At 5 mg/L Fe (II) the nitrite removal was nearly 80% which declined to 44% at 50 mg/L. This was attributed to low pH values which hindered anammox activity. The mass balance study of nitrogen in the anammox process revealed that gas production was highest at 5 mg/L of Fe (II) conforming that 5 mg/L of Fe (II) is the optimum dose of iron for enhancing anammox reaction.