化学
位阻效应
加合物
吡啶
结晶学
取代基
碘化物
二次谐波产生
立体化学
无机化学
药物化学
有机化学
激光器
物理
光学
作者
Elena Cariati,Dominique Roberto,Renato Ugo,Peter C. Ford,Simona Galli,Angelo Sironi
出处
期刊:Inorganic Chemistry
[American Chemical Society]
日期:2005-05-01
卷期号:44 (11): 4077-4085
被引量:120
摘要
The structural, emissive, and nonlinear optical properties of new CuI adducts with para-substituted trans-stilbazolic and pyridinic ligands are reported. Single-crystal X-ray diffraction results indicate that the para-substituent on the organic ligand greatly influences the structural motif by its steric (tert-butyl), electronic/steric (dimethylamino), or bridging-donor (cyano) properties so that two absolutely new structural motifs, polymeric and oligomeric, are found when trans-stilbazole and pyridine carry a dimethylamino group in the para-position. In addition, a surprising photoemission behavior is observed, being the solid-state emission of [CuI(trans-4-stilbazole)]n, [CuI(trans-4'-(dimethylamino)-4-stilbazole)]n, and [CuI(4'-tert-butyl-4-stilbazole)]n totally quenched. In the case of the noncentrosymmetric CuI adduct of trans-4'-(dimethylamino)stilbazole a discrete second harmonic generation (SHG) occurs.
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