Citric acid modified potato starch films containing microcrystalline cellulose reinforcement - properties and application

微晶纤维素 淀粉 材料科学 柠檬酸 极限抗拉强度 吸水率 纤维素 胶粘剂 复合材料 溶解度 玻璃化转变 化学工程 聚合物 化学 有机化学 工程类 图层(电子)
作者
Katarzyna Wilpiszewska,Zbigniew Czech
出处
期刊:Starch-starke [Wiley]
卷期号:66 (7-8): 660-667 被引量:52
标识
DOI:10.1002/star.201300093
摘要

Starch - StärkeVolume 66, Issue 7-8 p. 660-667 Research Article Citric acid modified potato starch films containing microcrystalline cellulose reinforcement – properties and application Katarzyna Wilpiszewska, Corresponding Author Katarzyna Wilpiszewska Polymer Institute, West Pomeranian University of Technology, Szczecin, Poland Correspondence: Dr. Katarzyna Wilpiszewska, Polymer Institute, West Pomeranian University of Technology, ul. Pulaskiego 10, Szczecin 70-322, Poland E-mail:[email protected] Fax: +48-91-449 42 47Search for more papers by this authorZbigniew Czech, Zbigniew Czech Institute of Organic Chemical Technology, West Pomeranian University of Technology, Szczecin, PolandSearch for more papers by this author Katarzyna Wilpiszewska, Corresponding Author Katarzyna Wilpiszewska Polymer Institute, West Pomeranian University of Technology, Szczecin, Poland Correspondence: Dr. Katarzyna Wilpiszewska, Polymer Institute, West Pomeranian University of Technology, ul. Pulaskiego 10, Szczecin 70-322, Poland E-mail:[email protected] Fax: +48-91-449 42 47Search for more papers by this authorZbigniew Czech, Zbigniew Czech Institute of Organic Chemical Technology, West Pomeranian University of Technology, Szczecin, PolandSearch for more papers by this author First published: 21 January 2014 https://doi.org/10.1002/star.201300093Citations: 28 Colour online: See the article online to view Figs. 2 and 6 in colour. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Abstract The preparation method of starch-based films cross-linked with citric acid (CA) and containing microcrystalline cellulose (MCC) has been described. The addition of MCC improved mechanical properties of polysaccharide films. Young's modulus and tensile strength increased from 42 to 96 MPa and from 2.6 to 3.9 MPa, respectively, for unfilled starch/CA films and similar system containing 15 wt% MCC, respectively. Moreover, the presence of cellulose filler influenced the thermal properties of starch-based material: with increasing MCC content glass transition (tan δ) increased from 108 up to 129°C, respectively, for unfilled system and containing 15 wt% MCC. Additionally, the hydrophilicity of starch-based films was reduced, as moisture absorption and solubility in water decreased. 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