MXenes公司
材料科学
最大相位
纳米点
化学工程
无定形固体
碳化物
纳米技术
复合材料
结晶学
工程类
化学
作者
Shunlong Zhang,Xiaoyan Li,Wentao Yang,Huajun Tian,Zhongkang Han,Hangjun Ying,Guoxiu Wang,Wei‐Qiang Han
标识
DOI:10.1021/acsami.9b13308
摘要
MXenes, synthesized from MAX, have emerged as new energy-storage materials for a good combination of metallic conductivity and rich surface chemistry. The reported MXenes are synthesized mostly from Al-based MAX. It is still a big challenge to synthesize MXenes from abundant Si-based MAX because of its strong Ti–Si bonds. Here, we report for the first time a high-energy ultrasonic cell-crushing extraction method to successfully prepare Ti3C2Tx MXenes from Si-based MAX using a single low-concentration etchant. This novel strategy for preparing MXenes has a high extraction efficiency and is a fast preparation process of less than 2 h for selective etching of Si. Furthermore, through the high-energy ball-milling technology, unique P–O–Ti bonded red phosphorus nanodot/Ti3C2Tx (PTCT) composites were successfully prepared, which enable superior electrochemical performance in lithium- and sodium-ion batteries because of the double-morphology structure, where the amorphous nano red phosphorus particles were strongly absorbed to Ti3C2Tx MXene sheets, facilitating the transport of alkali ions during cycling processes. This novel synthesis method of Ti3C2Tx MXenes from Si-based MAX and unique P–O–Ti bonded PTCT composites opens a new door for preparing high-performance MXene-based materials and facilitating the development of low-cost MXenes and other two-dimensional materials for next-generation energy storage.
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