催化作用
阿尔塔
氮气
氧化还原
化学
选择性催化还原
无机化学
有机化学
神学
哲学
作者
Zhiwen Chen,Jun‐Min Yan,Qing Jiang
标识
DOI:10.1002/smtd.201800291
摘要
Abstract Converting N 2 to NH 3 is an extremely valuable process but a long‐standing challenge in chemistry. The crux is the choice of catalysts, where single atomic catalysts (SAC) are always pursued as the altar of atomic catalysts. In this paper, double atomic catalysts (DAC) of TM 2 ‐C 2 N with SAC of TM‐C 2 N (TM = Cr, Mn, Fe, Co, and Ni) for nitrogen reduction reaction (NRR) are systematically compared. Unexpectedly, TM 2 ‐C 2 N are more suitable than TM‐C 2 N as catalysts for NRR. Moreover, the Mn 2 ‐C 2 N endows the highest catalytic activity with the lowest potential of −0.23 V versus RHE, which is the best among all reported calculation results for NRR under ambient conditions. As a result, a new way to design catalysts with DAC is provided.
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