Palladium(II)‐Catalyzed Synthesis of Dibenzothiophenes from 2‐Biphenylyl Disulfides by C−H Functionalization

Abstract The palladium‐catalyzed oxidative preparation of dibenzothiophene derivatives from 2‐biphenylyl disulfides by C−H functionalization is described herein. This procedure shows a high tolerance toward various functional groups and does not require the further addition of a metal oxidant, a base, or a ligand. Also, the present method was applied to the facile preparation of dibenzoselenophene.