塔菲尔方程
锰
析氧
催化作用
纳米棒
氧气
材料科学
纳米技术
化学工程
化学
冶金
工程类
电极
物理化学
有机化学
电化学
生物化学
作者
Gökhan Elmacı,Okan İçten,Demet Özer,Gökhan Özgenç,Zeliha Ertekin,Dursun Ali Köse,Kadi̇r Pekmez,Birgül Zümreoğlu‐Karan
出处
期刊:ChemNanoMat
[Wiley]
日期:2021-09-22
卷期号:7 (12): 1340-1347
被引量:4
标识
DOI:10.1002/cnma.202100256
摘要
Abstract The development of electrocatalysts for the OER (oxygen evolution reaction) process is an ongoing challenge in producing sustainable energy systems. Herein, we report QS (quasi‐spherical), IR (irregular), and NR (nanorod) Mn 2 OBO 3 (manganese oxoborate), modified with a carbon support, as candidate electrocatalysts for OER in a neutral medium. QS‐, IR‐ and NR‐Mn 2 OBO 3 catalysts displayed low onset potentials of 201 mV, 205 mV, and 208 mV and Tafel slope results of 94 mV dec −1 , 97 mV dec −1 , and 106 mV dec −1 , respectively. As a result of the long‐term stability tests, it was determined that the NR‐Mn 2 OBO 3 sample was extremely stable compared to the QS‐ and IR‐catalysts. This work introduces a new Mn 2 OBO 3 /C composite catalyst that displays efficient OER performance at a neutral medium and provides a different perspective for catalyst development strategies.
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