Hybrid Ionogel Electrolytes for Advanced Lithium Secondary Batteries: Developments and Challenges

Abstract Incidents in the use of lithium‐ion batteries are usually caused by the malfunction of flammable organic liquid electrolytes with poor thermal stability. Therefore, the development of noncombustible electrolytes is regarded as one of the most effective means to prevent the safety hazards of lithium‐ion batteries. Ionic liquids have attracted much interest recently, mainly due to their high ionic conductivity, low volatility, and incombustibility. The application of ionic liquids to the preparation of quasi‐solid‐state gel electrolytes combines the advantages of ionic liquids and avoids the risks of organic liquid electrolytes. Therefore, the solid‐state ionogels have been considered as a promising alternative electrolyte system, especially for the much‐desired energy storage devices with higher energy density and flexibility. This review focuses on the recent progress of ionogel electrolytes for lithium‐ion batteries. The preparation strategies for ionogel electrolytes based on different frameworks, namely inorganic matrix, organic matrix, and organic‐inorganic hybrid matrix, are discussed. Subsequently, efforts to improve the properties of the ionogel electrolytes, including the ionic conductivity, mechanical properties, and lithium‐ion transfer number, are summarized. Besides, the applications of ionogel electrolytes in high‐voltage lithium‐ion batteries and lithium metal batteries as well as the batteries under extreme environments are outlined. Finally, the perspectives on studying and improving the performances of ionogel electrolytes for advanced lithium‐ion batteries are provided.