材料科学
插层(化学)
阴极
电化学
钒
水溶液
无机化学
动力学
离子
钒酸盐
化学工程
电导率
电极
物理化学
化学
物理
有机化学
量子力学
工程类
冶金
作者
Quan Zong,Yanling Zhuang,Chaofeng Liu,Qiaoling Kang,Yuanzhe Wu,Jingji Zhang,Jiangying Wang,Daiwen Tao,Qilong Zhang,Guozhong Cao
标识
DOI:10.1002/aenm.202301480
摘要
Abstract For the development of aqueous zinc‐ion batteries, exploiting vanadium‐based cathode materials with quick kinetics and acceptable cycling stability is crucial. Herein, to achieve these goals, transition metal ions (Zn 2+ ) and organic ions (C 5 H 14 ON + and Ch + ) are introduced into layered hydrated V 2 O 5 . The intrinsic high conductivity of Ch + and the oxygen vacancies generated through ion pre‐intercalation accelerate the electrical mobility by optimizing the electronic structure. The Zn 2+ stabilizes the layered structure and the expanded interlayer spacing improves the ionic diffusivity. The synergistic effect of pre‐intercalated Zn 2+ and Ch + results in the (Zn 0.1 , Ch 0.1 )V 2 O 4.92 ·0.56H 2 O cathode exhibiting a discharge capacity of 473 mAh g −1 at 0.1 A g −1 with a high energy efficiency of 88% and excellent cycling stability with 91% retention after 2000 cycles at 4 A g −1 . Ex situ characterizations and density functional theory calculations reveal a reversible intercalation mechanism of Zn 2+ , and the improved electrochemical kinetics are attributed to the altered electronic conductivity and the reduced binding energy between Zn 2+ and host O 2− .
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