材料科学
聚吡咯
相变材料
聚乙二醇
热能储存
储能
热电效应
热的
气凝胶
聚乙烯
相变
相(物质)
太阳能
化学工程
热电发电机
功率(物理)
复合材料
工程物理
聚合物
化学
热力学
电气工程
有机化学
物理
工程类
聚合
作者
Shenghui Han,Feng Xiong,Mulin Qin,Zhenghui Shen,Haiwei Han,Yongkang Jin,Ali Usman,Yonggang Wang,Rui‐Qin Zhong,Ruqiang Zou
标识
DOI:10.1016/j.solmat.2024.112745
摘要
The efficient utilization of solar energy requires advanced heat storage technology, while phase change heat storage materials cannot utilize their high-density latent heat storage performance due to defects such as poor light absorption and leakage. To address these deficiencies, here, shape-stabilized phase change materials (SSPCMs) of polyethylene glycol (PEG) encapsulated by polypyrrole (PPy) aerogel were prepared through chemical polymerization and physical infiltration methods. Particularly, our findings demonstrated that PPy aerogel simultaneously enhances the shape stability and improves the solar-thermal conversion efficiency of PEG. The developed SSPCMs have a melting enthalpy of 142.4 J/g and 86% solar-thermal conversion efficiency. SSPCMs can maintain a stable shape, enthalpy value, and heat release time after 100 cycles. When used as a solar-thermal conversion material in a solar thermoelectric power generation system and thermal therapy, a long-term stable output voltage of 318 mV and temperature of 40–50 °C are generated, respectively, achieving effective conversion from renewable solar energy to applicable electricity and heat energy. This work may pave an effective way for the integrated design of encapsulating materials and light-absorbing materials in SSPCMs.
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