Ni/Co/Carbon nitride derived from ZIF-67 (MOF) nanocomposite: Enhanced light-driven photocatalytic degradation of methylparaben, mechanism & toxicity

A nickel oxide/cobalt/carbon nitride (Ni/Co/CN) nanocomposite synthesized via co-precipitation was used for the degradation of methylparaben (MEP). Various analytical techniques were used to ascertain the structural, optical, and electrochemical characteristics of the synthesized nanocomposite. The unique nature of the compound without any free particles over the CN was established. Photocatalytic degradation studies demonstrated the superiority of 3-Ni/Co/CN over bare NiO, Co/CN, 1-Ni/Co/CN, and 5-Ni/Co/CN. Near complete MEP degradation (100%) was achieved after 120 min of incubation with MEP 75 mg L-1 in acidic medium pH (3) for an initial concentration of 3-Ni/Co/CN (10 mg/100 mL). HPLC-MS/MS analysis was used to elucidate the degradation pathway, and the catalyst was found stable for four subsequent cycles. Hence, our nanocatalyst effectively degraded MEP. Furthermore, microbial, aquatic, and animal studies demonstrated the environmental efficiency of the synthesized nanomaterials.