电解
海水
材料科学
腐蚀
化学工程
电流密度
分解水
无机化学
电催化剂
电解水
阳极
电化学
冶金
化学
电极
催化作用
物理化学
有机化学
电解质
海洋学
物理
量子力学
工程类
地质学
光催化
作者
Suyu Ge,Ping Cheng,Yun Zhao,Haibo Jin,Yuefeng Su,Ning Li,Jingbo Li,Zhiyong Xiong,Caihong Feng,Daxin Shi
出处
期刊:Small
[Wiley]
日期:2024-11-06
标识
DOI:10.1002/smll.202406578
摘要
Abstract Producing hydrogen via seawater electrolysis is pivotal for addressing both energy and environmental crises. An industrial‐current‐density electrocatalyst consisting of Mo‐doped FeCoP nanorods decorated with MnO x nanosheets is elaborately designed and grows in situ on nickel foam forming hierarchical Mo‐FeCoP@MnO x /NF (M‐FCP@MnO x /NF) for seawater electrolysis. Density functional theory calculations demonstrate that MnO x species remarkably reduce the adsorption capacity of Cl − , which enhances the corrosion resistance and selectivity of M‐FCP@MnO x /NF during seawater electrolysis. Moreover, incorporating high‐valence Mo species forms a superficial electrostatic layer on electrocatalysts to repel Cl − . Owing to its enhanced double protection mechanism and unique self‐healing characteristics, M‐FCP@MnO x /NF requires overpotentials of only 209 mV (HER) and 270 mV (OER) to reach a current density of ≈1.0 A cm −2 and maintains stable operation over 120 h during alkaline electrolysis of seawater. The colorimetric analysis indicates negligible ClO − production post stability test, indicating that the OER selectivity approaches 100%.
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