电化学
背景(考古学)
有机合成
氮气
纳米技术
化学
材料科学
生化工程
有机化学
电极
催化作用
工程类
生物
物理化学
古生物学
标识
DOI:10.1016/j.gresc.2021.03.002
摘要
There is a resurgence of interests in organic electrochemistry, which is generally accepted as a green synthetic tool. In this context, many electrochemical methods have been developed in the past decade to access various nitrogen-centered radicals (NCRs) from readily available precursors in a controlled fashion, enabling the rapid development of many NCR-mediated new reactions for the construction of nitrogen-containing organic compounds. In this review, recent advances in the chemistry of electrochemically generated NCRs are critically highlighted, based on the electrochemical strategies for their formation and the types of NCRs. Focus is put on the mechanism for the electrochemical generation of different NCRs and their synthetic applications.
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