六氟丙烯
分离器(采油)
热稳定性
收缩率
复合数
材料科学
电解质
关闭
化学工程
复合材料
化学
聚合物
四氟乙烯
工程类
电极
核化学
热力学
共聚物
物理
物理化学
作者
Ming Xiong,Haolin Tang,Yadong Wang,Yun-Hsuan Lin,Meiling Sun,Zhuangfei Yin,Mu Pan
标识
DOI:10.1016/j.jpowsour.2013.04.064
摘要
PVDF–HFP/ePTFE composite separator with high thermal stability and low thermal shrinkage characteristic has been developed. The PVDF–HFP acts to absorb the electrolyte and shutdown at elevated temperature. The thermally stable ePTFE matrix is adopted to improve the mechanical strength and sustain the insulation after the shutdown. This novel separator presents good ion conductivity (up to 1.29 mS cm−1) and has a low thermal shrinkage of 8.8% at 162 °C. The composite separator shutdown at 162 °C and keep its integrity before 329 °C. Cells based on the composite separator show excellent capacities at high rate discharge and stable cycling performance.
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