Tunable Thermoresponsive Flexible Films for Adaptive Temperature Management and Visual Temperature Monitoring

Effective temperature management is essential for human thermal comfort and health. Although various temperature regulation materials have been proposed previously, there are few materials that have the dual functions of temperature monitoring and thermal management. Herein, a thermoresponsive form-stable flexible film based on phase-change materials (PCMs) and polydimethylsiloxane (PDMS) is rationally designed. The resultant versatile PCM@PDMS film is able to absorb and release heat responding to temperature stimuli and good mechanical strength. Moreover, optical visibility of the PCM@PDMS film can be reversibly converted between opaque and transparent states to monitor temperature. The switching principle is that solid PCMs embedded in the PDMS would be melted into liquid PCMs to enable light through the PCM@PDMS. The thermal experiment results suggest that the PCM@PDMS films can effectively regulate the human body temperature to adapt to the demanding environment (self-heating more than 3 °C in the cold environment or self-cooling more than 4 °C in the hot environment). Such dual-function films open a pathway to develop smart personalized thermoregulation materials for human body thermal management and temperature monitoring.