化学
硅烷化
卡宾
催化作用
激进的
组合化学
范围(计算机科学)
相容性(地球化学)
基质(水族馆)
分子
功能群
有机化学
计算机科学
化学工程
海洋学
工程类
程序设计语言
地质学
聚合物
作者
Huiwei Xu,Wanyao Zheng,Wen-Deng Liu,Yuqiao Zhou,Luqing Lin,Jiannan Zhao
出处
期刊:Organic Letters
[American Chemical Society]
日期:2023-07-24
卷期号:25 (30): 5579-5584
被引量:10
标识
DOI:10.1021/acs.orglett.3c01840
摘要
The construction of silicon-containing molecules has received increasing attention in recent years. Herein, we report the generation of silyl radicals through NHC catalysis under mild reaction conditions. This methodology offers a novel and convenient route to a diverse range of β-silyl ketones with a broad substrate scope and good functional group compatibility. Both the radical clock and electrochemical studies are consistent with the hypothesis of ground-state SET, and a plausible mechanism for the organocatalytic transformation is proposed.
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