咔唑
对映体
材料科学
机械容积
荧光
晶体结构
光化学
化学
结晶学
荧光粉
立体化学
光电子学
光学
物理
作者
Yitao Zheng,Letian Zhang,Zihao Huang,Shufeng Li,Lingqi Zuo,Yuanyuan Liang,Cong Liu,Suilian Luo,Guang Shi,Zujin Zhao,Fengqiang Sun,Bingjia Xu
标识
DOI:10.1002/chem.202202594
摘要
The development of circularly polarized thermally activated delayed fluorescence (CP-TADF) luminogens with stimuli-response characteristics remains challenging. Herein, a pair of organic enantiomers, S-CzTA and R-CzTA, with aggregation-induced emission properties, have been successfully developed by introducing chiral 1,2,3,4-tetrahydronaphthalene and carbazole to phthalimide. They present CP-TADF properties in toluene solutions, giving dissymmetric factors of 0.84×10-3 and -1.03×10-3 , respectively. In the crystalline state, both S-CzTA and R-CzTA can emit intense blue TADF and produce very bright sky-blue mechanoluminescence (ML) and remarkable mechanofluorochromism (MFC) under the stimuli of mechanical force. Single-crystal analysis and theoretical calculation results suggest that their ML activities are probably associated with their chiral and polar molecular structures and unique non-centrosymmetric molecular packing modes. Furthermore, the MFC properties of the enantiomers likely originate from the destruction of crystal structure, leading to the planarization of molecular conformation. This work may provide helpful guidance for developing new CP-TADF materials with force-stimuli-responsive properties.
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