材料科学
阴极
电化学
电极
钒
基质(水族馆)
水溶液
碳纤维
功率密度
化学工程
制作
复合数
纳米技术
复合材料
冶金
功率(物理)
替代医学
量子力学
化学
医学
海洋学
物理化学
病理
工程类
地质学
物理
作者
Sainan Liu,Xinxiang Chen,Qiang Zhang,Jiang Zhou,Zhenyang Cai,Anqiang Pan
标识
DOI:10.1021/acsami.9b12128
摘要
Coupling electrode materials with carbon substrates to construct flexible aqueous Zn-ion batteries (ZIBs) with excellent electrochemical performance is an attractive research focus. However, further improving the Zn2+/electron diffusion kinetics in such systems is still desirable. Herein, we present a novel hydrophilic carbon substrate that employs acid-treated natural halloysite and carbon nanotubes for the first time as structural and interfacial modifiers for loading V3S4 as a composite cathode (denoted as HCC-V3S4) for flexible ZIBs. The devices exhibit a high specific capacity of 148 mA h·g-1 under a current density of 0.5 A·g-1 (95% retention after 200 cycles), excellent rate performance, and a high energy density of 155.7 W h·kg-1, together with a high-power density of 5000 W·kg-1. The promising electrochemical property can be associated with the formation of the hydrophilic surface/interface and with the good conductivity of the composite electrode, which increases the Zn2+/electron transmission rate. Owing to the cost-effective design of the flexible substrate and the ZIB's impressive electrochemical performance, the fabricated device shows good potential applications in portable and wearable electronics.
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