Imidazole/pyridine-based ionic liquids modified metal-organic frameworks for efficient adsorption of Congo red in water

化学 吸附 离子液体 咪唑 吡啶 朗缪尔吸附模型 离子强度 无机化学 傅里叶变换红外光谱 刚果红 核化学 有机化学 水溶液 化学工程 催化作用 工程类
作者
Panpan Li,Zhe Li,Shangying Liu,Cuiping Li,Lei Ma,Chunliu Yang,Dandan Han,Can Niu,Xuelian Xin,Fugang Li
出处
期刊:Journal of Molecular Structure [Elsevier]
卷期号:1303: 137599-137599
标识
DOI:10.1016/j.molstruc.2024.137599
摘要

In this work, a metal-organic framework (MOF), {[Ba2L(NO3) (DMF)2] (DMF·H2O)}n, denoted as HBU-167, was synthesized under solvothermal conditions. HBU-167 obtained a 3D layer framework comprising the imidazole carboxylic acid ligand and Ba2+ as nodes. It was demonstrated to have an adsorption capacity for Congo red (CR), with an adsorption capacity of 407.37 mg•g−1 and a removal rate of 65.46%. To improve the adsorption capacity of HBU-167, simply impregnated three imidazole/pyridine-based ionic liquids (ILs) onto HBU-167 to obtain IL@HBU-167 for efficient CR adsorption. The results of Powder X-ray diffraction (PXRD), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM) revealed that ILs successfully bonded to HBU-167. Adsorption experiments on CR revealed that IL@HBU-167 exhibited increased stability as well as improved adsorption capacity. The adsorption capabilities of the IL@HBU-167 were 440.70 mg•g−1, 491.23 mg•g−1, and 544.56 mg•g−1, respectively, while the removal rates were 72.96%, 75.00%, and 83.28%, respectively. Batch experiments were applied to analyze the impact of factors such as contact time, initial concentration, pH, temperature, and ionic strength on the adsorption of CR by IL@HBU-167. The maximum adsorption capacity was observed at 25°C and pH = 6. The kinetic data indicated that the adsorption conformed to the pseudo-second-order kinetic model. The Langmuir isothermal model accurately described isothermal data. Furthermore, the adsorption capacity of IL@HBU-167 was investigated in real water samples from various sources. The results showed that IL@HBU-167 can be used as an innovative and inexpensive adsorbent for the removal of CR from water. The adsorption capacity was mainly derived from π-π, electrostatic interactions, and hydrogen bonding between IL@HBU-167 and CR.
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