材料科学
法拉第效率
阳极
电池(电)
电解质
阴极
钠离子电池
电化学
储能
离子
钠
电极
工艺工程
纳米技术
化学工程
电气工程
冶金
有机化学
物理化学
工程类
功率(物理)
化学
物理
量子力学
作者
Hanna He,Dan Sun,Yougen Tang,Haiyan Wang,Minhua Shao
标识
DOI:10.1016/j.ensm.2019.05.008
摘要
Sodium ion batteries have emerged as a potential low-cost candidate for energy storage systems due to the earth abundance and availability of Na resource. With the exploitation of high-performance electrode materials and in-depth mechanism investigation, the electrochemical properties of sodium ion batteries have been greatly improved. However, there are still various challenges need to be overcome before its commercial application. Among them, the low initial Coulombic efficiency of high-capacity anode is a critical issue that seriously limits the practical energy density of sodium ion full battery. This review firstly highlights the underlying mechanisms of the low initial Coulombic efficiency, such as the formation of SEI film from the decomposition of electrolyte, poor reversibility of sodiation/desodiation process, etc., and then summarizes the emerging strategies including electrolyte optimization, structure/morphology design, surface engineering, binder optimization and so on, to overcome them. Finally, some Na compensation strategies like pre-sodiated anode, sacrificial additives and sodium-rich cathode for practical application are discussed. This review provides pertinent insights into the challenges of initial Coulombic efficiency for the development of high energy sodium ion battery, which will benefit to its practical application.
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