Effective Proficiency of Manganese Porphyrins as Catalysts in Chemical Transformations: A Review
卟啉
催化作用
脱氢
锰
化学
解聚
有机化学
环加成
金属
光化学
组合化学
作者
Pankaj Kumar Chaurasia,Shashi Lata Bharati,Sunita Singh,Sudha Yadava
出处
期刊:Mini-reviews in Organic Chemistry [Bentham Science] 日期:2024-06-01卷期号:21 (4): 471-476
标识
DOI:10.2174/1570193x19666220513141040
摘要
: Porphyrin ligands are well-known for their promising tendency to produce metal porphyrin complexes of great significance. Out of different metal porphyrins, manganese porphyrins are one of the most valuable metal porphyrins due to effective catalytic performance and potential in many reactions like C-H isocyanation, the cycloaddition of CO2 with epoxides, epoxidation, oxygen reduction reaction, depolymerization reactions, oxidation of aromatic alcohols, selective oxidation of cycloalkenes/ alkanes, aliphatic C-H chlorination, dehydrogenation of alcohols, dye degradation, BSA nitration and others. Hence, in this review, the authors have best tried to present an effective insight overview of these aforementioned applications with the help of some recent studies for signifying the value of manganese porphyrins as a competent catalyst.