纤维素
溶解
溶解度
离子液体
化学
氢键
分子间力
极性(国际关系)
两亲性
分子
有机化学
化学工程
溶剂
氧化物
高分子化学
聚合物
共聚物
工程类
生物化学
细胞
催化作用
作者
Björn Lindman,Gunnar Karlström,Lars Stigsson
标识
DOI:10.1016/j.molliq.2010.04.016
摘要
Cellulose is insoluble in water and many organic solvents, but can be dissolved in a number of solvents of intermediate properties, like N-methylmorpholine N-oxide (NMMO) and ionic liquids (ILs). It can also be dissolved in water at high and low pHs, in particular if a cosolute of intermediate polarity is added. The insolubility in water is often referred to strong intermolecular hydrogen bonding between cellulose molecules. However, an examination of the interactions involved reveals another picture, which suggests that cellulose is significantly amphiphilic and that hydrophobic interactions are important for explaining the solubility pattern of cellulose.
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