电致变色
洋红
材料科学
聚合物
噻吩
电致变色装置
单体
透射率
化学工程
烷基
高分子化学
光化学
电极
化学
光电子学
有机化学
物理化学
复合材料
工程类
墨水池
作者
Xiaohong Chen,Qishu Qu
标识
DOI:10.1016/j.solmat.2017.12.017
摘要
A new magenta-to-transmissive electrochromic polymer, poly(3,4-bis(3-bromopropoxy)thiophene) (PBBrPOT) was synthesized by electrochemical polymerization and its electrochromic properties were characterized in detail. Compared with the representative "large-volume alkyl substituents" strategy, herein we use bromines as the end-capping groups of two propoxyl substituents on the 3- and 4- position of the thiophene ring to introduce more steric repulsion within the polymer chains, and therefore obtain a magenta neutral state of the polymer. The PBBrPOT film shows a set of reasonable electrochromic features, including low driving potentials (−0.1 V and 0.9 V), appropriate transmittance change (38% at 556 nm), but a relatively longer response time in bleaching process (t95 = 6.5 s).
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