烷基苯
X射线光电子能谱
热重分析
毛细管作用
毛细管电色谱
化学
傅里叶变换红外光谱
烯烃纤维
色谱法
分析化学(期刊)
元素分析
吡啶
扫描电子显微镜
红外光谱学
化学工程
材料科学
聚合物
催化作用
工程类
复合材料
有机化学
作者
Yun Guo,Wenjie Zhao,Shuyu Dai,Jian Mao,Qidong Zhang,Zhengkun Xie,Wenfen Zhang,Wuduo Zhao,Ajuan Yu,Shusheng Zhang
标识
DOI:10.1016/j.seppur.2023.123240
摘要
Herein, a highly stable (NAllyl)4-bridged alyzacalix[4]pyridine monolithic column (nAC4P@capillary) was fabricated by copolymerizing nAC4P with GMA and EDMA into a stationary phase through a simple olefin addition reaction. The physicochemical properties of the prepared materials were characterized by scanning electron microscopy (SEM), thermogravimetric analysis (TGA), energy dispersive X-ray (EDS), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FT-IR) and elemental analysis (EA). A wide range of analytes with various properties was well separated and demonstrated the synergistic effect of the various interaction sites. The maximum column efficiencies (Nmax) for all the analytes reached 62,368 plates/m, and the relative standard deviations (RSDs) of the daily retention times of alkylbenzenes, measured over six months were all lower than 5.63%. Non-covalent interaction analysis reveals that nAC4P@capillary can effectively combine the advantages of electronic configurations, π-π interactions, CH-π interactions, O–H…N hydrogen bonds and lone pair-π interactions, providing excellent prospects for high-performance chromatographic separation.
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