Fast and hydrosensitive switching of plasmonic nanocavities via photothermal effect

Metallic nanoplasmonics, due to its extremely small size and ultrafast speed, has been one of the key components for next-generation information technology. It is vital that the highly tunable nanoplasmonic system in the solid state can be achieved for optoelectronic devices, which, still remains elusive for the visible region. Here we sandwich vanadyl oxalate ( VOC 2 O 4 ) thin films in-between gold nanoparticles and gold film to establish thermo-responsive nanoantennas. The thickness of the VOC 2 O 4 composite films remains almost unchanged within the temperature cycles between 15°C and 80°C, while the refractive index of the films decreases with the increase of temperature due to the dehydration, which results in blueshift of the plasmon peak up to 60 nm. The plasmon resonances can be fully recovered when the temperature cools down again. This process is reversible within the temperature range of 15°C–80°C, which can be optically modulated with photothermal effect. Such thermo-responsive plasmonic nanoantenna works in the solid state with hundreds of kilohertz switching speed, which is highly compatible with traditional optoelectronic devices. It can be envisioned that this thermo-responsive optical thin film can be a promising candidate for integrated nanoplasmonic and optoelectronic devices.