Dispersion of Single-Walled Carbon Nanotubes in Aqueous Solutions of the Anionic Surfactant NaDDBS

The insolubility of single-walled carbon nanotubes (SWNT) in either water or organic solvents has been a limitation for the practical application of this unique material. Recent studies have demonstrated that the suspendability of SWNT can be greatly enhanced by employing appropriate surfactants. Although the efficiency of anionic, cationic, and nonionic surfactants has been demonstrated to different extents, the exact mechanism by which carbon nanotubes and the different surfactants interact is still uncertain. To deepen the understanding of this interfacial phenomenon, we have investigated the effects of chemical modifications of the surface on the extent of nanotube−surfactant interaction. Such changes in the surface chemistry of the SWNT can be achieved by simply varying the pretreatment method, which can be acidic or basic. We have found that intrinsic surface properties such as the PZC (point of zero charge) are greatly affected by the purification method. That is, the electrical charge of the SWNT surface varies with the pH of the surrounding media. However, it has been found that during the adsorption of the anionic surfactant sodium dodecylbenzenesulfonate (NaDDBS) on SWNT Coulombic forces do not play a central role, but are overcome by the hydrophobic interactions between the surfactant tail and the nanotube walls. Only at pH values far from the PZC do the Coulombic forces become important. The hydrophobic forces between the surfactant tail and the nanotube determine the structure of the surfactant-stabilized nanotubes. In such a structure, each nanotube is covered by a monolayer of surfactant molecules in which the heads form a compact outer surface while the tails remain in contact with the nanotube walls. It is important to note that although the final configuration can be described as a cylindrical micelle with a nanotube in the center, the mechanism of formation of this structure does not proceed by incorporation of a nanotube into a micelle, but rather by a two-step adsorption that ends up in the formation of a surfactant monolayer.