Rechargeable Sodium‐Ion Battery Based on Polyazaacene Analogue Anode

The high theoretical specific capacity, strong structural designability and relatively inexpensive manufacturing cost make the exploration of organic electrode materials more attractive in recent years. In this article, owing to the large π-conjugated structure, plenty of nitrogen heteroatoms and multiring aromatic system, polyazaacene analogue poly(1,6-dihydropyrazino[2,3 g]quinoxaline-2,3,8-triyl-7-(2H)-ylidene-7,8-dimethylidene) (PQL) was applied as the anode in sodium-ion batteries (SIBs). PQL was almost insoluble in conventional liquid organic electrolyte (1 M NaClO4 in ethylene carbonate (EC)/dimethyl carbonate (DMC) (v:v=1 : 1) with 5 % fluoroethylene carbonate (FEC)), which strongly improved its cycle stability. The initial discharge capacity was obtained to be 1825 mAh g-1 at the current density of 100 mA g-1 and stabilized at 317 mAh g-1 after 400 cycles with the coulombic efficiency as high as 97 %. It not only showed good rate capability at high current densities (202, 183 mAh g-1 at 1 A g-1 and 1.5 A g-1 ) but also had a superior energy density around 290 Wh kg-1 .