Structure, ionic motion and conductivity in some solid-solutions of the LiClMCl2 systems (M=Mg,V,Mn)

Abstract Three kinds of intermediate solid-solutions appear in the phase diagrams of the binary systems LiCl MCl2. They correspond to various distributions of ctions and vacancies in the available sites of a f.c.c. of chlorine atoms. The ionic motion of Li+ ions in the highly deficient solid-solutions has been concurrently investigated by NMR techniques and conductivity measurements.