五氯苯酚
化学
羟基自由基
水溶液
催化作用
水杨酸
活性炭
羟基苯甲酸
产量(工程)
核化学
降级(电信)
激进的
光化学
有机化学
吸附
电信
计算机科学
生物化学
材料科学
冶金
作者
Xie Quan,Yaobin Zhang,Shuo Chen,Yazhi Zhao,Fenglin Yang
出处
期刊:Journal of Molecular Catalysis A-chemical
[Elsevier]
日期:2007-02-01
卷期号:263 (1-2): 216-222
被引量:92
标识
DOI:10.1016/j.molcata.2006.08.079
摘要
Salicylic acid (SA, hydroxybenzoic acid) was used as molecular probe to determine hydroxyl radical (OH) in aqueous solutions, where microwave (MW) radiation was involved and activated carbon (AC) existed. Rapid reaction of OH with SA produced a stable fluorescence product, 2,3-dihydroxybenzoic acid (2,3-DHBA) as well as its homologue, 2,5-DHBA, which were determined by HPLC. Dose of AC, air supply, and MW power proved to be key factors influencing OH generation under MW radiation. The rate of OH generation reached 0.036 μmol s−1, and the OH yield reached 3.2 μmol in 3 min under a given condition. OH is an active species with high oxidative activity and can initiate free radical reactions. Another experiment was carried out to confirm that organic substance may degrade in aqueous solution by the MW assisted catalytic process. Pentachlorophenol (PCP) was used as target. Results showed that nearly 72–100% degradation (corresponding to 40% and 82% TOC removal) was observed in 60 min for two levels of PCP concentrations (500 and 2000 mg L−1), which implies that continuous production of OH during MW radiation supports free radical reactions that benefit PCP degradation.
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