Simultaneous electrocatalytic hydrogenation of aldehydes and phenol over carbon-supported metals

苯甲醛 糠醛 化学 催化作用 无机化学 电化学 苯酚 有机化学 电极 物理化学
作者
Udishnu Sanyal,Katherine Koh,Laura C. Meyer,Abhi Karkamkar,Oliver Y. Gutiérrez
出处
期刊:Journal of Applied Electrochemistry [Springer Science+Business Media]
卷期号:51 (1): 27-36 被引量:36
标识
DOI:10.1007/s10800-020-01464-7
摘要

Electrocatalytic hydrogenation of furfural, benzaldehyde, and phenol was studied on carbon-supported Rh, Ru, Pd, and Cu catalysts. All metals were active for hydrogenation of the carbonyl group in furfural and benzaldehyde, but only Rh/C was active for phenol hydrogenation. The intrinsic activities for furfural and benzaldehyde conversion were Pd/C < Ru/C ≤ Rh/C < Cu/C and Ru/C < Rh/C < Pd/C < Cu/C, respectively. While the trend in furfural hydrogenation remained the same in the presence of phenol, the trend in benzaldehyde hydrogenation in the presence of phenol changed to Rh/C < Ru/C < Pd/C < Cu/C. The Faradaic efficiencies for hydrogenation of both furfural (in the 10–40% range) and benzaldehyde (in the 45–100% range) followed the trend: Cu/C < Rh/C < Ru/C < Pd/C. When phenol and an aldehyde were present in the reactant solution, phenol hydrogenation was suppressed. In contrast, enhancements in the rates of carbonyl reduction were observed for both aldehydes in presence of phenol. Such enhancements depend on both the aldehyde and the metal catalyst. The enhancing factors for hydrogenation of furfural and benzaldehyde were in the 1.5–2 and 2–4 ranges, respectively. We conclude that intermolecular interactions between adsorbed phenol and the aldehydes is a general phenomenon that can potentially enhance the rates of carbonyl hydrogenation. This work highlights co-adsorption effects that pose both challenges and advantages for electrocatalytic reduction of organic compounds.
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