光催化
罗丹明B
煅烧
光降解
可见光谱
催化作用
亚甲蓝
甲基橙
光化学
材料科学
离子交换
离子
化学
光电子学
有机化学
作者
Mina Sabri,Aziz Habibi‐Yangjeh,Hushan Chand,Venkata Krishnan
标识
DOI:10.1016/j.seppur.2020.117268
摘要
In this work, novel TiO2/FeOCl photocatalysts were prepared trough calcination process and they were utilized as visible-light-induced photocatalysts for eliminating various pollutants in the presence of persulfate (PS) ions. Structural, morphological, photoelectrochemical, textural, and optical features of the obtained photocatalysts were extensively analyzed. The experimental outcomes illustrated that the weight percentage of FeOCl has significant impact on the photodegradation capability of the nanocomposites and the TiO2/FeOCl (20%) photocatalyst has the best photocatalytic efficiency in degradation of methylene blue (MB), methyl orange (MO), rhodamine B (RhB), and fuchsine. The elimination rate constant of RhB over the TiO2/FeOCl (20%) photocatalyst in the existence of 1.48 mM of PS ions was almost 36.1, 10.9, 8.5, and 24.8-times larger than the pure TiO2, PS ions, TiO2/PS, and TiO2/FeOCl (20%) sample, respectively. The improved photocatalytic ability was assigned to the more absorption of visible light and more inhibition of the charge carriers from recombination. Lastly, based on the heterojunction formation at the interface of n-TiO2, and n-FeOCl semiconductors, the photocatalytic mechanism in the presence of PS ions was discussed.
科研通智能强力驱动
Strongly Powered by AbleSci AI