同音
纳米团簇
化学
结晶学
材料科学
纳米技术
金属
有机化学
作者
Xian‐Kai Wan,Zong‐Jie Guan,Quan‐Ming Wang
标识
DOI:10.1002/ange.201706021
摘要
Abstract For the first time total structure determination of homoleptic alkynyl‐protected gold nanoclusters is reported. The nanoclusters are synthesized by direct reduction of PhC≡CAu, to give Au 44 (PhC≡C) 28 and Au 36 (PhC≡C) 24 . The Au 44 and Au 36 nanoclusters have fcc‐type Au 36 and Au 28 kernels, respectively, as well as surrounding PhC≡C‐Au‐C 2 (Ph)Au‐C≡CPh dimeric “staples” and simple PhC≡C bridges. The structures of Au 44 (PhC≡C) 28 and Au 36 (PhC≡C) 24 are similar to Au 44 (SR) 28 and Au 36 (SR) 24 , but the UV/Vis spectra are different. The protecting ligands influence the electronic structures of nanoclusters significantly. The synthesis of these two alkynyl‐protected gold nanoclusters indicates that a series of gold nanoclusters in the general formula Au x (RC≡C) y as counterparts to Au x (SR) y can be expected.
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