Superiority of Modified Polymeric Membrane with Nanomaterial on Temperature and Mechanical Stability and Application in Industrial Waste Water

材料科学 纳米材料 化学工程 聚合物 热稳定性 石墨烯 磁导率 氧化物 涂层 纳米复合材料 复合材料 纳米技术 冶金 化学 生物化学 工程类
作者
Canan Onaç,Ahmet Kaya,Necip Atar,İzzet Şener,H. Korkmaz Alpoğuz
出处
期刊:ECS Journal of Solid State Science and Technology [The Electrochemical Society]
卷期号:9 (6): 061019-061019 被引量:8
标识
DOI:10.1149/2162-8777/aba725
摘要

In this paper, we investigated the superiotires of carbon-based nanomaterial polymer inclusion membrane (PIM-GO) against to polymer inclusion membrane and removed Cr(VI), a highly toxic element typically used in chromate conversion coating in the plating industry, from the chrome plating water by using a PIM-GO modified with graphene oxide (GO), which strengthens the mechanical structure and permeability of PIMs. We performed experiments to investigate the membrance performance and structural ability ofthe PIM-GO, and lastly compared its performance to that of the PIM. We observed the PIM-GO's high selectivity and recovery (96.83%) in the removal of Cr(VI). GO added to the membrane structure caused a visible increase in the rate constant, permeability and flux.The PIM-GO affords opportunities to work with a wider range of pH levels, changes of which in membrane-based experiments with unmodified PIM shave caused significant decreases in flux and permeability. The ease of use, applicability, high permeability of the PIM-GO at high temperatures afford significant advantages over the unmodified membrane as well. The results of this study can aid the development of next-generation membranes with increased mechanical stability, the resistance to multilayered GO membranes, and the use of the membranes in industrial applications. Moreover, the high transport efficiency of the PIM-GO at temperatures exceeding room temperature is evidence of the improved thermal stability of the PIM-GO. In effect, our findings can inform the production of new membranes with increased mechanical stability, membrane lifetime, and usability in industrial applications.
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