Enantioselective Construction of Si‐Stereogenic Center via Rhodium‐Catalyzed Intermolecular Hydrosilylation of Alkene

Abstract Catalytic, enantioselective synthesis of stereogenic silicon compounds remains a challenge. Herein, we report a rhodium‐catalyzed regio‐ and enantio‐selective intermolecular hydrosilylation of alkene with prochiral dihydrosilane. This new method features a simple catalytic system, mild reaction conditions and a wide functional group tolerance.