Recent Advances on Conductive 2D Covalent Organic Frameworks

Abstract As a burgeoning family of crystalline porous copolymers, covalent organic frameworks (COFs) allow precise atomic insertion of organic components in the topology construction to form periodic networks and ordered nanopores. Their 2D networks bear great similarities to graphene analogs, and therefore are essential additions to the 2D family. Here, the electronic properties of conductive 2D‐COFs are reviewed and their bonding strategies and structural characteristics are examined in detail. The controlling approaches toward the morphologies of conductive 2D‐COFs are further explored, followed by a discussion of their applications in field‐effect transistors, photodetectors, sensors, catalysis, and energy storage. Finally, research challenges and forthcoming developments are projected. The resulting survey reveals that the extended porous 2D organic networks with conductive properties will provide great opportunities and essential innovations in various electronics and energy‐related fields.