Synthesis of Hollow CdxZn1−xSe Nanoframes through the Selective Cation Exchange of Inorganic–Organic Hybrid ZnSe–Amine Nanoflakes with Cadmium Ions

Angewandte Chemie International EditionVolume 51, Issue 13 p. 3211-3215 Communication Synthesis of Hollow CdxZn1−xSe Nanoframes through the Selective Cation Exchange of Inorganic–Organic Hybrid ZnSe–Amine Nanoflakes with Cadmium Ions† Xuan Wu, Xuan Wu Department of Chemistry, School of Science, Tianjin University, Tianjin 300072 (P. R. China)Search for more papers by this authorYifu Yu, Yifu Yu Department of Chemistry, School of Science, Tianjin University, Tianjin 300072 (P. R. China)Search for more papers by this authorYang Liu, Yang Liu Department of Chemistry, School of Science, Tianjin University, Tianjin 300072 (P. R. China)Search for more papers by this authorYou Xu, You Xu Department of Chemistry, School of Science, Tianjin University, Tianjin 300072 (P. R. China)Search for more papers by this authorCuibo Liu, Cuibo Liu Department of Chemistry, School of Science, Tianjin University, Tianjin 300072 (P. R. China)Search for more papers by this authorProf. Dr. Bin Zhang, Corresponding Author Prof. Dr. Bin Zhang [email protected] Department of Chemistry, School of Science, Tianjin University, Tianjin 300072 (P. R. China)Department of Chemistry, School of Science, Tianjin University, Tianjin 300072 (P. R. China)Search for more papers by this author Xuan Wu, Xuan Wu Department of Chemistry, School of Science, Tianjin University, Tianjin 300072 (P. R. China)Search for more papers by this authorYifu Yu, Yifu Yu Department of Chemistry, School of Science, Tianjin University, Tianjin 300072 (P. R. China)Search for more papers by this authorYang Liu, Yang Liu Department of Chemistry, School of Science, Tianjin University, Tianjin 300072 (P. R. China)Search for more papers by this authorYou Xu, You Xu Department of Chemistry, School of Science, Tianjin University, Tianjin 300072 (P. R. China)Search for more papers by this authorCuibo Liu, Cuibo Liu Department of Chemistry, School of Science, Tianjin University, Tianjin 300072 (P. R. China)Search for more papers by this authorProf. Dr. Bin Zhang, Corresponding Author Prof. Dr. Bin Zhang [email protected] Department of Chemistry, School of Science, Tianjin University, Tianjin 300072 (P. R. China)Department of Chemistry, School of Science, Tianjin University, Tianjin 300072 (P. R. China)Search for more papers by this author First published: 14 February 2012 https://doi.org/10.1002/anie.201108098Citations: 103 † This work was financially supported by the National Natural Science Foundation of China (20901057 and 11074185), National Basic Research Program of China (2009CB939901), the Tianjin Natural Science Foundation (10JCYBJC01800), State Key laboratory of Crystal Material at Shandong University (KF0910), and Innovation Foundation of Tianjin University. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat Graphical Abstract Tiny frames: The selective cation-exchange of unpurified ZnSe–diethylenetriamine (DETA) hybrid nanosheets with cadmium ions, followed by the dissolution of DETA and subsequent Ostwald ripening, leads to hollow CdxZn1−xSe nanoframes with tunable compositions (see scheme). These nanoframes are highly active in the photocatalytic hydrogen evolution from water-splitting. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description anie_201108098_sm_miscellaneous_information.pdf1.1 MB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume51, Issue13March 26, 2012Pages 3211-3215 RelatedInformation