Efficient treatment of actual glyphosate wastewater via non-radical Fenton-like oxidation

Compared to radical oxidative pathway, recent research revealed that non-radical oxidative pathway has higher selectivity, higher adaptability and lower oxidant requirement. In this work, we have designed and synthesized Cu2O/Cu nanowires (CuNWs), by pyrolysis of copper chloride and urea, to selectively generate high-valent copper (CuIII) upon H2O2 activation for the efficient treatment of actual glyphosate wastewater. The detailed characterizations confirmed that CuNWs nanocomposite was comprised of Cu0 and Cu2O, which possessed a nanowire-shaped structure. The electron paramagnetic resonance (EPR) analysis, in situ Raman spectra, chronoamperometry and liner sweep voltammetry (LSV) verified CuIII, which mainly contributed to glyphosate degradation, was selectively generated from CuNWs/H2O2 system. In particular, CuI is mainly oxidized by H2O2 into CuIIIvia dual-electron transfer, rather than simultaneously releasing OH• via single electron transfer. More importantly, CuNWs/H2O2 system exhibited the excellent potential in the efficient treatment of actual glyphosate wastewater, with 96.6% degradation efficiency and chemical oxygen demand (COD) dropped by 30%. This novel knowledge gained in the work helps to apply CuNWs into heterogeneous Fenton-like reaction for environmental remediation and gives new insights into non-radical pathway in H2O2 activation.